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1.
激光测厚具有安全可靠、测量精度高、测量范围大等优点,广泛应用于纸张、电池极片等薄膜类材料厚度的在线测量。带材宽幅方向扫描测厚时由于扫描架往复运动会产生机械振动,影响在线测厚精度。针对该问题,以锂离子电池极片厚度测量为例,使用双激光差动式测厚平台对电池极片和铜箔分别进行厚度测量,然后对测厚数据进行频谱分析,探究其振动规律的相似性,并基于频谱分析结果采用滑动带阻滤波方式对测厚数据进行处理,滤波后极片和铜箔的厚度极差分别降低了33.4%和73.8%,有效过滤了机械振动导致的测量误差,可满足极片和铜箔厚度测量的精度要求。 相似文献
2.
Chenfei Shi Yuling Su Jinjin Guo Jiangying Zhang Gaoshang Gong Huiyun Hu Yongqiang Wang 《Ceramics International》2021,47(8):10887-10892
In this paper, the crystal structure, vacancy defect, local electron density and magnetic properties of Gd1-xCaxCrO3 (0 ≤ x ≤ 0.3) polycrystalline samples were investigated systematically. The crystal structural analyses show that all the samples are orthorhombic phase and a structural distortion happens around x = 0.3. Due to the formation of Cr4+ ions, both the lattice constant and the Cr–O bond length decrease. The results of positron annihilation spectrum reveals that the vacancy defect concentration increases and the local electron structure changes with the introduction of Ca2+ ions. The field-cooled (FC) and zero-field cooled (ZFC) curves of Gd1-xCaxCrO3 samples measured under H = 100 Oe exhibits negative magnetization characteristics due to the interaction between Gd3+ and Cr3+ ions, and the magnetism can be affected by the structural distortion. 相似文献
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4.
《Ceramics International》2022,48(22):33167-33176
This study evaluates the luminescence performance of fired clay bricks coated with SrAl2O4:Eu/Dy phosphor. To do so, SrAl2O4:Eu/Dy phosphor was first produced using the traditional solid-state reaction synthesis technique. The prepared phosphor was then used for coating fired clay bricks to analyze the luminescence performance via spectral analysis, decay characteristics, and microstructure of the bricks. The results reveal that excitation and emission spectra of the phosphor coated bricks range from 200 to 480 nm and 455 to 650 nm, respectively, suggesting that the phosphor coated bricks have the capacity of absorbing light with a wide range of wavelengths. The peak wavelength projected at 511 nm in the emission spectrum is achieved, which indicates 4f65 d1-4f7 transition of Europium (Eu2+). The repeated excitation and deexcitation of Eu2+ by using hole traps and trap levels offered by Dysprosium (Dy3+), exist between the ground and the excited state of Eu2+ leads to luminescent phenomenon. Moreover, the decay characteristics has revealed that phosphor coated bricks can emit light for a considerable amount of time (>8.5 min) upon the removal of the excitation source. The results reveal that phosphor coated bricks has the potential of increasing energy efficiency of residential and commercial buildings. 相似文献
5.
《Ceramics International》2022,48(11):15252-15260
The Co3O4, as a potential anode of lithium-ion batteries, has gained considerable attention because of high theoretical capacity. However, the Co3O4 is suffering from serious structure deterioration and rapid capacity fading due to its bulky volume change during cyclic charge/discharge process. Herein, to stabilize the lithium storage performance of the Co3O4 nanoparticles, a characteristic carbon scaffold (HPC) integrating hollow and porous structures has been fabricated by a well-designed method for the first time. The ultrafine Co3O4 nanoparticles are cleverly anchored on the HPC (HPC@Co3O4) and hence achieve significantly improved electrochemical properties including high capacity, improved reaction kinetics and outstanding cycle stability, showing high capacity of 1084.7 mAh g-1 after 200 cycles at 200 mA g-1 as well as 681.4 mAh g-1 after 300 cycles at 1000 mA g-1. The HPC@Co3O4 therefore shows good promising for application in advanced lithium-ion battery anodes. The results of the systematically material and electrochemical characterizations indicate that the synergistic effects of ultrafine Co3O4 nanoparticles and well-designed HPC scaffolds are responsible for the outstand performance of the HPC@Co3O4 anode. Moreover, this work can enrich the understanding and development of stable and high-performance metal oxide-based lithium-ion battery anodes for advanced lithium storage. 相似文献
6.
The deterministic and probabilistic prediction of ship motion is important for safe navigation and stable real-time operational control of ships at sea. However, the volatility and randomness of ship motion, the non-adaptive nature of single predictors and the poor coverage of quantile regression pose serious challenges to uncertainty prediction, making research in this field limited. In this paper, a multi-predictor integration model based on hybrid data preprocessing, reinforcement learning and improved quantile regression neural network (QRNN) is proposed to explore the deterministic and probabilistic prediction of ship pitch motion. To validate the performance of the proposed multi-predictor integrated prediction model, an experimental study is conducted with three sets of actual ship longitudinal motions during sea trials in the South China Sea. The experimental results indicate that the root mean square errors (RMSEs) of the proposed model of deterministic prediction are 0.0254°, 0.0359°, and 0.0188°, respectively. Taking series #2 as an example, the prediction interval coverage probabilities (PICPs) of the proposed model of probability predictions at 90%, 95%, and 99% confidence levels (CLs) are 0.9400, 0.9800, and 1.0000, respectively. This study signifies that the proposed model can provide trusted deterministic predictions and can effectively quantify the uncertainty of ship pitch motion, which has the potential to provide practical support for ship early warning systems. 相似文献
7.
The heat and mass transfer of unsteady magnetohydrodynamic (MHD) flow of Newtonian fluid with Hall current and ion-slip currents due to vast possible engineering applications is very important in areas like power generators, MHD accelerators, refrigeration coils, electric transformers, and heating elements. A quality-based research on Hall and ion-slip consequences on the rotating unsteady MHD flow past an infinite perpendicular moving absorbent plate have not been performed. Therefore, the Hall and ion-slip consequences on rotating unsteady MHD flow past an infinite perpendicular moving absorbent plate have not been performed. The similarity transformations are engaged to transfer the governing partial differential equations within favor of the scheme of nonlinear ordinary differential equations and elucidated numerically making use of cubic B-splines collocation mechanism. The influences of felicitous parameters on basic equations are remarked on through graphical profiles. Even though the computational estimations of frictional forces, Nusselt number, and Sherwood number for various parameters are distributed in tabular format and exchanged of views comparatively. 相似文献
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9.
《International Journal of Hydrogen Energy》2022,47(9):6217-6226
The development of electrocatalysts with high activity and durability for oxygen reduction reaction (ORR) in acidic electrolyte environments remains a serious challenge for clean and efficient energy conversion. Synergistic effects between Pt and inexpensive metals, the d band center of Pt and catalyst morphology could adjust the adsorption and desorption of oxygen intermediates by the Pt. All the factors affect the catalytic performance of Pt-based nanocrystals. Here, we prepared Cu@PtCu3 NWs with an average diameter of 74.9 nm for Cu and about 10 nm PtCu3 layer. After etching, the Cu@PtCu3 nanowires is transformed into PtCu nanotube structure, due to the removal of copper from the surface and interior. PtCu NTs for ORR shows excellent activities and durability due to the integration of structural advantages and synergistic effects. Notably, the mass activity and specific activity of PtCu NTs (0.105 A mg?1Pt and 0.230 mA cm?2Pt) are 2.0 and 3.8 times higher than that of commercial Pt/C (0.053 A mg?1Pt and 0.06 mA cm?2Pt). The etching process to change the morphology of the catalyst and alter the electronic structure of the catalyst is expected to be useful for the design of future structured Pt-based alloy nanocatalysts. 相似文献
10.
Jiajia Suo Bowen Yang Edoardo Mosconi Hyeon-Seo Choi YeonJu Kim Shaik M. Zakeeruddin Filippo De Angelis Michael Grätzel Hui-Seon Kim Anders Hagfeldt 《Advanced functional materials》2021,31(34):2102902
Surface passivation treatment is a widely used strategy to resolve trap-mediated nonradiative recombination toward high-efficiency metal-halide perovskite photovoltaics. However, a lack of passivation with mixture treatment has been investigated, as well as an in-depth understanding of its passivation mechanism. Here, a systematic study on a mixed-salt passivation strategy of formamidinium bromide (FABr) coupled with different F-substituted alkyl lengths of ammonium iodide is demonstrated. It is obtained better device performance with decreasing chain length of the F-substituted alkyl ammonium iodide in the presence of FABr. Moreover, they unraveled a synergistic passivation mechanism of the mixed-salt treatment through surface reconstruction engineering, where FABr dominates the reformation of the perovskite surface via reacting with the excess PbI2. Meanwhile, ammonium iodide passivates the perovskite grain boundaries both on the surface and top perovskite bulk through penetration. This synergistic passivation engineer results in a high-quality perovskite surface with fewer defects and suppressed ion migration, leading to a champion efficiency of 23.5% with mixed-salt treatment. In addition, the introduction of the moisture resisted F-substituted groups presents a more hydrophobic perovskite surface, thus enabling the decorated devices with excellent long-term stability under a high humid atmosphere as well as operational conditions. 相似文献